washing soda = caustic soda = drain cleaner = Sodium hydroxide = very alkali
careful when mixing with any acid - such as vinegar/citric/acetic/etc - expect a reaction like foaming .......
Generally any electrolysis process will cause some 'fizzing' as gas's are released from the metals - different from the foam caused by acid+alkyd reaction.
Gases released can be flammable - best to do outside (think exploding batteries....).
Oh yes - a lead acid battery if 'pushed' too hard (asked to give a LOT of AMPS) can also explode.
Enjoy yourself guys experimenting, but please wear glasses of some form - skin burns, more or less heal - eyes don't.
Never stopped me, but then again i have so much metal in one eye (die grinding) i cannot have an MRI ......
Washing soda and caustic soda are not the same chemical, another use for washing soda is to relax muscles. You can bathe in washing soda. Sodium carbonate
However vinegar is acetic acid, I drink it. It is safe, keeps scurvy away as well. As well as pickling foods.Including Rollmops.
Citric acid is used in cooking and again is safe.
Washing Soda - sorry, you are correct - reading one thing, thinking another.
You still get a reaction with an acid, be it a Carbonate or Hydroxide, only difference is the gas given off - one explosive the other, not.
Tried acetic and citric acid ...... sorry but life's too short for me to wait on something happening - even after chucking a fish-tank heater in to warm things up.
3-4 weeks, i expect the rust killed, the paint applied and the tank fitted and filled with petrol, within that time scale!
Acetic acid fumes get to my asthma so i don't consider it that benign (nice on F & C's though).
The expensive Rust Killer - 5L of EVAPORE or something was bloody slow reacting - i say expensive because it seems to be nothing more than citric acid - see previous thread on the subject.
As for keeping scurvy away - i think Cpt Cook would disagree with you, it had a very limited effect - however it was an excellent disinfectant and used right into the late 19th century by the navy.
Anyway good luck finding a the ultimate solution ... do like idea of electrolysis though - just fitted an old sacrificial anode to my trailer in an attempt to stop it rusting.
i used to be Lab/R&D Manager for a Centrifuge company and did all the 'dodgy' jobs - mainly cos i've no sense of smell.
I was once dragged out our 'fume-room' after collapsing on Hexane fumes - I think my eyes were like your family ....